Both send email well. The difference is what they know about your customers. Klaviyo was built around ecommerce data and pulls detailed order, product and browsing information from Shopify. Mailchimp is a general-purpose tool with a Shopify connection, friendlier to start with and less deep once you want to segment on what people bought.
If you are not sure, the platform finder asks seven questions about how you work and suggests three platforms.